The Dental Board code of conduct 3.6 states
Good practice involves:
considering the young person’s capacity for decision-making and consent; in general, where a practitioner judges that a person is of a sufficient age and of sufficient mental and emotional capacity to give consent to a service, then that person should be able to request and provide informed consent to receive services without the consent of a parent, guardian or other legal representative
In light of the code, assuming the sister has appropriate authority, you are perfectly correct in requesting the sister be involved in the decision making around treatment and document accordingly.
There are many different activities that require consent, and any patient is able to withdraw consent at any time. Consider the example of a 5 year old requiring treatment. A parent might consent, but if the child does not consent, then treatment will not progress.
In this situation, there are two consent processes, the right of the patient to consent or not to the sister being present, and the ability (or not) of the patient to consent to treatment. Remember that the patient has the right to refuse to consent to have the sister present. In this situation, where the patient is unable to consent to treatment due to lack of comprehension, then you would seek consent from the patient to discuss with the sister at another time. If this is refused, then you are unable to gain consent, and you would not continue with treatment.